EUROPIUM

(Eu), chemical element, rare-earth metal of transition Group IIIb of the periodic table; it is the least dense, softest, and most volatile member of the lanthanide series. The element was discovered (1896) by Eugne-Anatole Demaray and named for Europe. One of the least abundant rare earths, it occurs in minute amounts in many rare-earth minerals such as monazite and also in the products of nuclear fission. Europium is usually separated by reducing it to the +2 oxidation state and precipitating it with sulfate ions. The primary use of europium has been for research purposes. Because it readily absorbs thermal neutrons, it may prove to be of use in nuclear-reactor control rods. It has been used as a phosphor activator, as a component of certain electronic materials, and as an agent in the manufacture of fluorescent glass. The metal has been prepared by electrolysis of the fused halides and by reduction of its oxide by lanthanum metal followed by distillation of the europium metal. It quickly reacts in air, oxygen, and water. Both of its naturally occurring isotopes are stable: europium-151 (47.8 percent) and europium-153 (52.2 percent). In its predominant trivalent state, europium behaves as a typical rare earth, forming a series of generally pale pink salts. The Eu3+ ion is paramagnetic because of the presence of unpaired electrons. Europium possesses the most easily produced and stablest +2 oxidation state of the rare earths. Trivalent europium solutions can be reduced by zinc metal and hydrochloric acid to give Eu2+ in solution; the ion is stable in dilute hydrochloric acid if oxygen from the air is excluded. A series of white to pale yellow or green europium(II) salts are known, such as europium(II) sulfate, chloride, hydroxide, and carbonate. The divalent halides may be prepared by hydrogen reduction of the anhydrous trivalent halides. atomic number 63 atomic weight 151.965 melting point 822 C boiling point 1,527 C specific gravity 5.244 (25 C) valence 2, 3 electronic config. 2-8-18-25-8-2 or (Xe)4f 75d06s2