(adv.) An inseparable prefix, or particle, signifying not; in-; non-. In- is prefixed mostly to words of Latin origin, or else to words formed by Latin suffixes; un- is of much wider application, and is attached at will to almost any adjective, or participle used adjectively, or adverb, from which it may be desired to form a corresponding negative adjective or adverb, and is also, but less freely, prefixed to nouns. Un- sometimes has merely an intensive force; as in unmerciless, unremorseless.
UN-
Meaning of UN- in English
Webster's English dictionary. Английский словарь Webster. 2012